In situ surface analysis in selective oxidation catalysis:: n-butane conversion over VPP

In situ analysis of the surface of a working selective oxidation catalyst is an essential yet rarely conducted experiment in attempts to derive structure-function relationships. The case study of n-butane oxidation over vanadyl pyrophosphate (VPP) is used to develop a general working hypothesis and to illustrate that the molecular properties of the substrate sets boundary conditions on the surface chemical properties of the catalyst. Experiments using in situ X-ray photoelectron spectroscopy (XPS) and in situ low-energy X-ray absorption spectroscopy are used to derive compositional, electronic, and geometric structural information of the surface of the working VPP. These data allow the conclusion that a surface phase different from VPP must be present covering at least part of the active material. The recent data together with literature observations are used to derive a scenario explaining the function of VPP as a unique catalytic system.