Fullerene C60 immobilized in polymethylmethacrylate film as an optical temperature sensing material

被引:11
作者
Amao, Y [1 ]
Okura, I
机构
[1] Natl Aerosp Lab, Fluid Sci Res Ctr, Chofu, Tokyo 1828522, Japan
[2] Tokyo Inst Technol, Dept Bioengn, Midori Ku, Yokohama, Kanagawa 2268501, Japan
关键词
optical temperature sensing; fullerene; fluorescence quenching; Arrhenius activation energy; polymer film;
D O I
10.1051/analusis:2000154
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A new optical temperature sensor based on the fluorescence intensities of the fullerene C-60 immobilized in polymethylmethacrylate (PMMA) film was developed. The fluorescence intensity of the C-60 film decreased with increasing the temperature in the range 260-373 K. Arrhenius plot of ln[(I(T)/I(T-ref))] versus 1/T for the C-60 film exhibits considerable linearity supported by the correlation factor, r(2), estimated to be 0.989 by the least squares method (T-ref = 260 K). The E/R value of the C-60 film is estimated to be 22.3 K. These results indicate that the C-60 film provides a linear temperature response in the range 260-373 K.
引用
收藏
页码:847 / 849
页数:3
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