Measurement of spin diffusion and intermolecular distances between chemically equivalent nuclei in rotating solids

被引：20

作者：

Tekely, P ^{[1
]}

Potrzebowski, MJ

Dusausoy, Y

Luz, Z

机构：

[1] Univ Nancy 1, Lab Methodol RMN, UPRESA CNRS 7042, FU CNRS E008 INCM, F-54506 Vandoeuvre Nancy, France

[2] Univ H Poincare, LCM3B, UPRESA CNRS 7036, Nancy 1, France

[3] Weizmann Inst Sci, Dept Chem Phys, IL-76100 Rehovot, Israel

[4] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90362 Lodz, Poland

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 291卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(98)00632-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The one-dimensional exchange experiment ODESSA (Gerardy-Montouillout et al., J. Magn. Reson. A 123 (1996) 7-15) has been applied for measuring spectral spin diffusion rate constants between chemically equivalent C-13 spins in carbonyl groups. The feasibility of using these spin diffusion rate constants for determining intermolecular distances up to 9 Angstrom has been tested on some singly labeled model compounds. (C) 1998 Elsevier Science B.V. All rights reserved.

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页码：471 / 479

页数：9

相关论文

共 19 条

[1] C-13 SPIN DIFFUSION OF ADAMANTANE [J].

BRONNIMAN, CE ;

SZEVERENYI, NM ;

MACIEL, GE .

JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (08) :3694-3700

[2] SPECTRAL SPIN-DIFFUSION UNDER N=0 ROTATIONAL RESONANCE [J].

CHALLONER, R ;

KUMMERLEN, J ;

MCDOWELL, CA .

MOLECULAR PHYSICS, 1994, 83 (04) :687-700

[3] TWO-DIMENSIONAL EXCHANGE NMR IN ROTATING SOLIDS - A TECHNIQUE TO STUDY VERY SLOW MOLECULAR REORIENTATIONS [J].

DEJONG, AF ;

KENTGENS, APM ;

VEEMAN, WS .

CHEMICAL PHYSICS LETTERS, 1984, 109 (04) :337-342

[4] THE CRYSTAL-STRUCTURE OF BENZOIC-ACID - A REDETERMINATION WITH X-RAYS AT ROOM-TEMPERATURE - A SUMMARY OF NEUTRON-DIFFRACTION WORK AT TEMPERATURES DOWN TO 5K [J].

FELD, R ;

LEHMANN, MS ;

MUIR, KW ;

SPEAKMAN, JC .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1981, 157 (3-4) :215-231

[5] Shift-independent nuclear spin diffusion by slow magic-angle sample spinning for the exploration of solids [J].

Gan, ZH ;

Ernst, RR .

CHEMICAL PHYSICS LETTERS, 1996, 253 (1-2) :13-19

[6] ODESSA, a new 1D NMR exchange experiment for chemically equivalent nuclei in rotating solids [J].

GerardyMontouillout, V ;

Malveau, C ;

Tekely, P ;

Olender, Z ;

Luz, Z .

JOURNAL OF MAGNETIC RESONANCE SERIES A, 1996, 123 (01) :7-15

[7] INVESTIGATION OF EXCHANGE PROCESSES BY 2-DIMENSIONAL NMR-SPECTROSCOPY [J].

JEENER, J ;

MEIER, BH ;

BACHMANN, P ;

ERNST, RR .

JOURNAL OF CHEMICAL PHYSICS, 1979, 71 (11) :4546-4553

[8] PRECISION NEUTRON-DIFFRACTION STRUCTURE DETERMINATION OF PROTEIN AND NUCLEIC-ACID COMPONENTS .3. CRYSTAL AND MOLECULAR STRUCTURE OF AMINO-ACID ALPHA-GLYCINE [J].

JONSSON, PG ;

KVICK, A .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1972, B 28 (06) :1827-&

[9] SPECTRAL SPIN DIFFUSION IN POLYCRYSTALLINE SOLIDS UNDER MAGIC-ANGLE SPINNING [J].

KUBO, A ;

MCDOWELL, CA .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1988, 84 :3713-3730

[10] Local structure in spider dragline silk investigated by two-dimensional spin-diffusion nuclear magnetic resonance [J].

Kümmerlen, J ;

van Beek, JD ;

Vollrath, F ;

Meier, BH .

MACROMOLECULES, 1996, 29 (08) :2920-2928