Magnetic field effects on nickel electrodeposition - II. A steady-state and dynamic electrochemical study

被引:54
作者
Devos, O [1 ]
Aaboubi, O [1 ]
Chopart, JP [1 ]
Merienne, E [1 ]
Olivier, A [1 ]
Amblard, J [1 ]
机构
[1] UFR Sci, CNRS, EP Dynam Transferts Interfaces 120, F-51687 Reims 02, France
关键词
D O I
10.1149/1.1838927
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A very recent paper, referred to below as Paper I, had been devoted to the description of magnetic field effects on the structural features of nickel electrodeposits grown from a Watts solution,either pure or in the presence of small amounts of a primary brightener and leveling agent such as 2-butyne-1,4-diol (BD). The conclusions of Paper I stressed the major effect of the magnetic field which was supposed to come down to a magnetohydrodynamic forced convection close to the cathodic interface. This convection enhances those among the cathodic reactions which are likely to be mass-transport controlled, which is the case for the hydrogen electrode reaction as well as for the catalytic hydrogenation undergone by ED on the cathodic surface. The aim of this paper is to describe the results of electrochemical studies which have been carried out with the same system so as to check the validity of our assumption.
引用
收藏
页码:4135 / 4139
页数:5
相关论文
共 25 条
  • [1] MAGNETIC-FIELD EFFECTS ON MASS-TRANSPORT
    AABOUBI, O
    CHOPART, JP
    DOUGLADE, J
    OLIVIER, A
    GABRIELLI, C
    TRIBOLLET, B
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (06) : 1796 - 1804
  • [2] AABOUBI O, 1991, THESIS U REIMS FRANC
  • [3] INHIBITION AND NICKEL ELECTROCRYSTALLIZATION
    AMBLARD, J
    EPELBOIN, I
    FROMENT, M
    MAURIN, G
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1979, 9 (02) : 233 - 242
  • [4] Amblard J, 1977, OBERFLACHE SURF, V18, P1
  • [5] DIFFUSION PROCESS IN VISCOUS-FLOW OF ELECTROLYTE SOLUTION IN MAGNETOHYDRODYNAMIC PUMP ELECTRODES
    AOGAKI, R
    FUEKI, K
    MUKAIBO, T
    [J]. DENKI KAGAKU, 1976, 44 (02): : 89 - 94
  • [6] Aogaki R., 1975, DENKI KAGAKU, V43, P509
  • [7] QUARTZ-CRYSTAL ELECTROGRAVIMETRY WITH CONTROLLED HYDRODYNAMICS - APPLICATIONS TO THE STUDY OF NICKEL ELECTRODEPOSITION
    ARKAM, C
    BOUET, V
    GABRIELLI, C
    MAURIN, G
    PERROT, H
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (09) : L103 - L105
  • [8] THE KINETICS OF NICKEL ELECTRODEPOSITION - INHIBITION BY ADSORBED HYDROGEN AND ANIONS
    CHASSAING, E
    JOUSSELLIN, M
    WIART, R
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 157 (01): : 75 - 88
  • [9] Flow modulation as a means of studying leveling agents
    Cheng, CC
    West, AC
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (02) : 560 - 564
  • [10] ELECTRODEPOSITION AND ELECTRODISSOLUTION OF COPPER WITH A MAGNETIC-FIELD - DYNAMIC AND STATIONARY INVESTIGATIONS
    CHOPART, JP
    DOUGLADE, J
    FRICOTEAUX, P
    OLIVIER, A
    [J]. ELECTROCHIMICA ACTA, 1991, 36 (3-4) : 459 - 463