Entangled coordination networks with inherent features of polycatenation, polythreading, and polyknotting

被引：428

作者：

Wang, XL

Qin, C

Wang, EB ^{[1
]}

Li, YG

Su, ZM

Xu, L

Carlucci, L

机构：

[1] NE Normal Univ, Inst Polyoxometalate Chem, Dept Chem, Changchun 130024, Peoples R China

[2] Univ Milan, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 36期

关键词：

coordination modes; networks; nickel; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200501373

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Caught in a net: Self-assembly of nickel salts with 4,4′-bipyridine and the long V-shaped 4,4′-oxybis(benzoate) ligand has led to three different coordination networks: a parallel polycatenation of nanotube motifs to give a layered framework (see picture), a 2D → 3D polythreaded array involving five polymeric units at a time, and a 3D self-penetrating binodal network with an unprecedented (4.82) (4.64.8 4.10) topology. (Figure Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5824 / 5827

页数：4

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