Determination of the C-7, 9, 12, 13, 17 and 18 stereochemistries of tautomycetin. Synthesis of the tautomycetin degradation product

被引：9

作者：

Dai, JP ^{[1
]}

Sodeoka, M ^{[1
]}

Shibasaki, M ^{[1
]}

机构：

[1] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 04期

关键词：

D O I：

10.1016/0040-4039(95)02188-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Syntheses of the degradation product 3 of tautomycetin (1) and its diastereoisomers have been achieved. Comparison of the spectral data of these diastereoisomers with those of the degradation product of natural 1 indicates that tautomycetin has the 7R,9S,12S,13S,17S,18R stereochemistry.

引用

页码：491 / 494

页数：4

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