Structural studies of the distorted perovskite Ca0.25Cu0.75TiO3

被引：78

作者：

Moussa, SM ^{[1
]}

Kennedy, BJ ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Heavy Met Res Ctr, Sydney, NSW 2006, Australia

来源：

MATERIALS RESEARCH BULLETIN | 2001年 / 36卷 / 13-14期

基金：

澳大利亚研究理事会;

关键词：

oxides; neutron scattering; crystal structure;

D O I：

10.1016/S0025-5408(01)00732-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The crystal structure of Ca0.25Cu0.75TiO3 has been studied between 25 and 1000 degreesC using powder neutron diffraction methods. The diffraction data is well described in space group N-3, and there is no indication of any crystallographic phase transition. The preference of the Jahn-Teller active Cu ion for square planar geometry is believed to be a significant factor in the stabilization of the observed structure. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2525 / 2529

页数：5

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