[2-(2-Acetyl-2-ethoxycarbonyl-1-methoxy-ethyl)-8-quinolinolato-C,N,O](pyridine-N)-palladium(II)

被引:13
作者
Billodeaux, DR [1 ]
Fronczek, FR
Yoneda, A
Newkome, GR
机构
[1] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA
[2] Himeji Inst Technol, Fac Engn, Dept Appl Chem, Himeji, Hyogo 67122, Japan
[3] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
关键词
D O I
10.1107/S0108270198005538
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, [Pd(C17H17NO5)(C5H5N)], is the diastereomer with opposite configurations at the two chiral centers, and is racemic. The two independent molecules in the asymmetric unit differ in conformation primarily by a rotation of 167.0(6)degrees about the C-C-ester bond. The Pd-O bond lengths are 2.105(3) and 2.080 (3) Angstrom, and the Pd-C distances are 2.106(4) and 2.117 (3) Angstrom.
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页码:1439 / 1441
页数:3
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