Asymmetric Diels-Alder: Monobenzylated isosorbide and isomannide as highly effective chiral auxiliaries

被引：44

作者：

Loupy, A

Monteux, D

机构：

[1] Lab. des Reactions Selectives sur S., Associé au CNRS, Université de Paris-Sud, 91405, Orsay

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 39期

关键词：

D O I：

10.1016/0040-4039(96)01539-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Lewis acid promoted Diels-Alder reactions of acrylate esters from monobenzylated isosorbide or isomannide and cyclopentadiene provided exclusively endo-adducts with good yields and high diastereoselectivities. The R/S selectivities are quasi total and opposed using either isosorbide or isomannide derivatives. Copyright (C) 1996 Published by Elsevier Science Ltd

引用

页码：7023 / 7026

页数：4

共 16 条

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