Viscosities of the ternary mixture (1-butanol plus n-hexane plus 1-chlorobutane) at 298.15 K and 313.15 K

被引:30
作者
Dominguez, M [1 ]
Santafe, J [1 ]
Lopez, MC [1 ]
Royo, FM [1 ]
Urieta, JS [1 ]
机构
[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ Quim Fis, Area Quim Fis,Secc Quim, E-50009 Zaragoza, Spain
关键词
viscosity; alkanol; alkane; chloroalkane; ternary mixtures;
D O I
10.1016/S0378-3812(98)00377-X
中图分类号
O414.1 [热力学];
学科分类号
摘要
Viscosities of the ternary mixture (1-butanol + n-hexane + 1-chlorobutane) and the binary mixture (n-hexane + 1-chlorobutane) have been measured at 298.15 K and 313.15 K. Viscosity deviations and excess Gibbs energy of activation of viscous flow for the binary and ternary systems were fitted to Redlich-Kister's and Cibulka's equations. The 'viscosity-thermodynamic' model (UNIMOD) has been used to correlate experimental data for the binary mixtures and to predict the viscosities for the ternary system. The Group-Contribution Thermodynamic-Viscosity model (GC-UNIMOD), and the group contribution method proposed by Wu have been used to predict the viscosity of the binary and ternary systems. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:133 / 148
页数:16
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