Chemical Technologies for Exploiting and Recycling Carbon Dioxide into the Value Chain

被引:602
作者
Peters, Martina [1 ,2 ]
Koehler, Burkhard [1 ]
Kuckshinrichs, Wilhelm [4 ]
Leitner, Walter [3 ]
Markewitz, Peter [4 ]
Mueller, Thomas E. [1 ]
机构
[1] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, CAT Catalyt Ctr, D-52074 Aachen, Germany
[2] Bayer Technol Serv GmbH, D-51368 Leverkusen, Germany
[3] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
[4] Forschungszentrum Julich, Inst Energie & Klimaforsch Syst Forsch & Technol, D-52425 Julich, Germany
关键词
carbon dioxide fixation; catalysis; energy conversion; industrial chemistry; renewable resources; ENHANCED-OIL-RECOVERY; KOLBE-SCHMITT CARBONATION; MASS-TRANSFER MODEL; NICKEL(0)-CATALYZED CYCLOADDITION COPOLYMERIZATION; SUPERCRITICAL-FLUID IMPREGNATION; C-H BONDS; FORMIC-ACID; ALTERNATING COPOLYMERIZATION; DIMETHYL CARBONATE; CO2; CAPTURE;
D O I
10.1002/cssc.201000447
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
While experts in various fields discuss the potential of carbon capture and storage (CCS) technologies, the utilization of carbon dioxide as chemical feedstock is also attracting renewed and rapidly growing interest. These approaches do not compete; rather, they are complementary: CCS aims to capture and store huge quantities of carbon dioxide, while the chemical exploitation of carbon dioxide aims to generate value and develop better and more-efficient processes from a limited part of the waste stream. Provided that the overall carbon footprint for the carbon dioxide-based process chain is competitive with conventional chemical production and that the reaction with the carbon dioxide molecule is enabled by the use of appropriate catalysts, carbon dioxide can be a promising carbon source with practically unlimited availability for a range of industrially relevant products. In addition, it can be used as a versatile processing fluid based on its remarkable physicochemical properties.
引用
收藏
页码:1216 / 1240
页数:25
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