Halide redistribution in Pd-catalysed 1,6-diene cycloisomerisation

被引:25
作者
Bray, KL [1 ]
Fairlamb, IJS [1 ]
Lloyd-Jones, GC [1 ]
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
关键词
D O I
10.1039/b009356o
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
[(MeCN)(3)PdCl](+), generated in situ, reversibly disproportionates to give [(MeCN)(2)PdCl2] and [(MeCN)(4)Pd](2+). The neutral species is a reactive and highly regioselective catalyst for 1,6-diene cycloisomerisation.
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页码:187 / 188
页数:2
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