Cyanide-bridged lanthanide-transition metal one-dimensional arrays {(DMF)(10)Yb-2[Ni(CN)(4)](3)}(infinity) and {(DMF)(10)Yb-2[Pt(CN)(4)](3)}(infinity)

被引:80
作者
Knoeppel, DW [1 ]
Shore, SG [1 ]
机构
[1] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210
关键词
D O I
10.1021/ic9600846
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The one-dimensional arrays {(DMF)(10)Yb-2[Ni(CN)(4)](3)}(infinity) (1) and {(DMF)(10)Yb-2[Pt(CN)(4)](3)}(infinity) (2) were prepared from the metathesis reactions of YbCl3 and K2Ni(CN)(4) or K2Pt(CN)(4) in DMF (DMF = N,N-dimethylformamide). Unlike other one-dimensional structures adopted by complexes of M(CN)(4)(2-) anions, two unusual array structures were obtained.
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页码:1747 / &
页数:3
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