Isomerization of linear to angular [3]phenylene and PAHs under flash vacuum pyrolysis conditions

被引：23

作者：

Dosa, PI

Schleifenbaum, A

Vollhardt, KPC ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Ctr New direct Organ Synth, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 07期

关键词：

D O I：

10.1021/ol015519u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Flash vacuum pyrolysis (FVP) of linear [S]phenylene affords its angular counterpart and the same mixture of polycyclic aromatic hydrocarbon isomers as that observed on RIP of angular [3]phenylene, A mechanism, supported by a C-13 labeling study, is proposed to explain these results.

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页码：1017 / 1020

页数：4

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