Enhanced optical limiting in derivatized fullerenes

被引：85

作者：

Smilowitz, L ^{[1
]}

McBranch, D ^{[1
]}

Klimov, V ^{[1
]}

Robinson, JM ^{[1
]}

Koskelo, A ^{[1
]}

Grigorova, M ^{[1
]}

Mattes, BR ^{[1
]}

Wang, H ^{[1
]}

Wudl, F ^{[1
]}

机构：

[1] UNIV CALIF SANTA BARBARA,INST POLYMERS & ORGAN SOLIDS,SANTA BARBARA,CA 93106

来源：

OPTICS LETTERS | 1996年 / 21卷 / 13期

关键词：

D O I：

10.1364/OL.21.000922

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We have observed enhanced optical limiting behavior in solutions of a derivatized fullerene (phenyl-C-61-butyric acid cholesteryl ester) from 532 to 700 nm. Transient absorption measurements determined the spectral and temporal regions of interest for optical limiting in C-60 and in C-60 derivatives that are due to a reverse saturable absorption mechanism and predicted enhanced limiting at longer wavelengths. Intensity-dependent transmission measurements made at several wavelengths confirmed these results. The increased solubility and the broadened ground-state absorption of the functionalized C-60 make it suitable for use as an optical limiter in the red and the near infrared. (C) 1996 Optical Society of America.

引用

页码：922 / 924

页数：3

共 14 条

[1] BENTIVEGNA F, 1993, APPL PHYS LETT, V62, P1721, DOI 10.1063/1.109585
[2] HEFLIN JR, 1994, POLYM PREPR, V35, P238
[3] PREPARATION AND CHARACTERIZATION OF FULLEROID AND METHANOFULLERENE DERIVATIVES
HUMMELEN, JC
KNIGHT, BW
LEPEQ, F
WUDL, F
YAO, J
WILKINS, CL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (03) : 532 - 538
[4] OPTICAL LIMITING WITH C-60 IN POLYMETHYL METHACRYLATE
KOST, A
TUTT, L
KLEIN, MB
DOUGHERTY, TK
ELIAS, WE
[J]. OPTICS LETTERS, 1993, 18 (05) : 334 - 336
[5] C-60 DERIVATIVES EMBEDDED IN SOL-GEL SILICA FILMS
MAGGINI, M
SCORRANO, G
PRATO, M
BRUSATIN, G
INNOCENZI, P
GUGLIELMI, M
RENIER, A
SIGNORINI, R
MENEGHETTI, M
BOZIO, R
[J]. ADVANCED MATERIALS, 1995, 7 (04) : 404 - 406
[6] MCBRANCH D, 1995, P SOC PHOTO-OPT INS, V2530, P195
[7] MCBRANCH D, 1994, KP SPIE, V2284, P15
[8] NONLINEAR ABSORPTION STUDY OF A C-60-TOLUENE SOLUTION
MCLEAN, DG
SUTHERLAND, RL
BRANT, MC
BRANDELIK, DM
FLEITZ, PA
POTTENGER, T
[J]. OPTICS LETTERS, 1993, 18 (11) : 858 - 860
[9] BOTTLENECK OPTICAL LIMITERS - THE OPTIMAL USE OF EXCITED-STATE ABSORBERS
MILES, PA
[J]. APPLIED OPTICS, 1994, 33 (30): : 6965 - 6979
[10] ENHANCED REVERSE SATURABLE ABSORPTION AND OPTICAL LIMITING IN HEAVY-ATOM-SUBSTITUTED PHTHALOCYANINES
PERRY, JW
MANSOUR, K
MARDER, SR
PERRY, KJ
ALVAREZ, D
CHOONG, I
[J]. OPTICS LETTERS, 1994, 19 (09) : 625 - 627

← 1 2 →