Preparation of polypyrrole microstructures by direct electrochemical oxidation of pyrrole in an aqueous solution of camphorsulfonic acid

被引：110

作者：

Qu, LT ^{[1
]}

Shi, GQ ^{[1
]}

Yuan, JY ^{[1
]}

Han, GY ^{[1
]}

Chen, F ^{[1
]}

机构：

[1] Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2004年 / 561卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

polypyrrole; microstructure; electrochemical oxidation;

D O I：

10.1016/j.jelechem.2003.07.028

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Polypyrrole microstructures with morphology like bowls, cups and bottles have been generated electrochemically by direct oxidation of pyrrole in an aqueous solution of camphorsulfonic acid. The well-ordered microstructures stand upright on the working electrode surface in a high density. Their morphological features can be easily controlled by changing the electrochemical polymerization conditions and the results have good reproducibility. The growth process of microstructures was studied by scanning electron microscopy and optical microscopy. Based on the experimental observations, a self-assembled gas bubble template mechanism was postulated. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：149 / 156

页数：8

共 34 条

[1] Conducting polymer artificial muscles [J].

Baughman, RH .

SYNTHETIC METALS, 1996, 78 (03) :339-353

[2]

Beh WS, 1999, ADV MATER, V11, P1038, DOI 10.1002/(SICI)1521-4095(199908)11:12<1038::AID-ADMA1038>3.0.CO

[3]

2-L

[4]

Bernier P., 1999, ADV SYNTHETIC METALS

[5] Preparation of polymeric micro- and nanostructures using a template-based deposition method [J].

Cepak, VM ;

Martin, CR .

CHEMISTRY OF MATERIALS, 1999, 11 (05) :1363-1367

[6] Toward colloidal dispersions of template-synthesized polypyrrole nanotubules [J].

De Vito, S ;

Martin, CR .

CHEMISTRY OF MATERIALS, 1998, 10 (07) :1738-+

[7]

DECKER C, 1989, P SPIE INT SOC OPT, V112, P1022

[8]

Fu MX, 2001, ADV MATER, V13, P1874, DOI 10.1002/1521-4095(200112)13:24<1874::AID-ADMA1874>3.0.CO

[9]

2-M

[10] Electrochemical fabrication of aligned microtubular heterojunctions of poly(p-phenylene) and polythiophene [J].

Fu, MX ;

Chen, F ;

Zhang, JX ;

Shi, GQ .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (08) :2331-2333

← 1 2 3 4 →