Hydrotelluration of alkynes:: a unique route to Z-vinyl organometallics

被引:38
作者
Vieira, ML
Zinn, FK
Comasseto, JV
机构
[1] Univ Sao Paulo, Inst Quim, BR-05599970 Sao Paulo, Brazil
[2] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil
关键词
hydrotelluration; vinylic tellurides; transmetallation; coupling reactions; tellurium;
D O I
10.1590/S0103-50532001000500003
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The hydrotelluration reaction of alkynes is reviewed. The transformation of vinylic tellurides into reactive vinyl organometallics and the coupling reactions of vinylic tellurides with alkynes and organometallics are presented.
引用
收藏
页码:586 / 596
页数:11
相关论文
共 86 条
[1]  
[Anonymous], 1998, TRANSITION METALS OR
[2]   Addition of Z-vinylic higher order cyanocuprates to hindered enones.: The influence of the reaction conditions [J].
Araújo, MA ;
Barrientos-Astigarraga, RE ;
Ellensohn, RM ;
Comasseto, JV .
TETRAHEDRON LETTERS, 1999, 40 (28) :5115-5118
[3]  
ARAUJO MA, 1995, SYNLETT, P1145
[4]   Carbon-carbon bond formation by means of organotellurium compounds [J].
Barrientos-Astigarraga, RE ;
Castelani, P ;
Comasseto, JV ;
Formiga, HB ;
da Silva, NC ;
Sumida, CY ;
Vieira, ML .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 623 (1-2) :43-47
[5]   Highly unsaturated conjugated systems from vinylic tellurides [J].
Barrientos-Astigarraga, RE ;
Moraes, DN ;
Comasseto, JV .
TETRAHEDRON LETTERS, 1999, 40 (02) :265-268
[6]   HYDROTELLURATION OF ACETYLENES - SYNTHESIS OF VINYLIC TELLURIDES, DIVINYL TELLURIDES, AND 1-(ORGANYLTELLURO)-1,3-BUTADIENES [J].
BARROS, SM ;
DABDOUB, MJ ;
DABDOUB, VMB ;
COMASSETO, JV .
ORGANOMETALLICS, 1989, 8 (07) :1661-1665
[7]   VINYLLITHIUMS FROM BUTYL-VINYL TELLURIDES AND BIS-VINYL TELLURIDES [J].
BARROS, SM ;
COMASSETO, JV ;
BERRIEL, J .
TETRAHEDRON LETTERS, 1989, 30 (52) :7353-7356
[8]   CONVENIENT SYNTHESIS OF TELLUROPHENE [J].
BARTON, TJ ;
ROTH, RW .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 39 (02) :C66-&
[9]  
BATESON JH, 1994, ORGANOMETALLIC REAGE
[10]   Stereoselective addition of sodium organyl chalcogenolates to alkynylphosphonates: synthesis of diethyl 2-(organyl)-2-(organochalcogenyl)vinylphosphonates [J].
Braga, AL ;
Alves, EF ;
Silveira, CC ;
de Andrade, LH .
TETRAHEDRON LETTERS, 2000, 41 (02) :161-163