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Conjugated oligoenynes based on the diethynylethene unit

被引：228
作者：
Nielsen, MB
Diederich, F
机构：
[1] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark
[2] ETH Honggerberg, Organ Chem Lab, CH-8093 Zurich, Switzerland
来源：
CHEMICAL REVIEWS | 2005年 / 105卷 / 05期
关键词：
D O I：
10.1021/cr9903353
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Acetylinic scaffolding with suitably functionalized DEEs and TEEs has provided a large selection of extended, carbon-rich chromophores that are formally derived from parent classes of linear and cyclic oligoalkenes. This review covers general synthetic procedures for DEEs and TEEs, their reactivities, and their chromophoric and redox properties in comparison to the extended, linear, or cyclic oligomeric structures.
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页码：1837 / 1867
页数：31
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