Improvement of the superconducting transport properties of YBa2Cu3O7-δ by BaZrO3 doping

We have doped the YBa2Cu3O7-delta,S superconducting ceramics with BaZrO3 up to 75 wt.% and studied the changes of some physical properties. The most important finding is the enhancement of the critical current density, which has a maximum at around 5 wt.% doping level. Compared with the undoped samples, the critical current density is four times higher if the doping compound is introduced prior to the calcination treatment, or two times higher if BaZrO3 is introduced prior to the sintering treatment, The dependence of the critical current density on the doping level is consistent with the dependence of the Seebeck coefficient. We also observed a very small decrease of the critical temperature. The real density of the samples decreases with increasing doping level as expected from the ratio between the theoretical densities of YBa2Cu3O7-delta and BaZrO3, the effect being important for doping levels higher than 25 wt.%.