Linking centered manganese triangles into larger clusters:: A {Mn32} truncated cube

被引：100

作者：

Scott, RTW

Parsons, S

Murugesu, M

Wernsdorfer, W

Christou, G

Brechin, EK

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[3] CNRS, Lab Louis Neel, F-38042 Grenoble, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 40期

关键词：

cluster compounds; magnetic properties; manganese; O ligands; tripodal ligands;

D O I：

10.1002/anie.200501881

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cutting Corners: Elaborate triangular arrays of Mn ions are stabilized by the tripodal ligand 1,1,1-tris(hydroxymethyl)-ethane. The self-assembled {Mn32} truncated cube (see picture) is further stabilized by end-on-bridging azide ligands and acetate groups. Such stabilization could prove to be useful in the preparation of single-molecule magnets. (Chemical Equation Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：6540 / 6543

页数：4

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