Novel superelectrophilic complexes for low-temperature alkane and cycloalkane transformations

被引：17

作者：

Akhrem, IS ^{[1
]}

Orlinkov, AV ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 05期

关键词：

aluminum halides; superelectrophiles; transformations of alkanes and cycloalkanes;

D O I：

10.1007/BF02498141

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The results of studies on the elaboration of new superelectrophilic complexes and their use for efficient low-temperature transformations of alkanes and cycloalkanes, such as cracking, isomerization, alkylation, and single-step functionalization (acylation, carbonylation, ionic monobromination, sulfurization, thioacylation, etc.), are summarized. The activity of new aprotic organic and inorganic superacids is compared to that of known electrophilic systems, including protic superacids. The reasons for the superelectrophilic properties of new active systems are considered.

引用

页码：740 / 764

页数：25

共 207 条

[1]

ADRIANUS J, 1940, Patent No. 2249366

[2] DIRECT ALKYLACYLATION OF ARENES BY ALKANES AND CYCLOALKANES IN THE PRESENCE OF APROTIC SUPERACIDS [J].

AKHREM, I ;

ORLINKOV, A ;

VOLPIN, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (03) :257-258

[3] A NOVEL FAMILY OF APROTIC ORGANIC SUPERACIDS FOR LOW-TEMPERATURE ALKANE AND CYCLOALKANE TRANSFORMATIONS [J].

AKHREM, I ;

ORLINKOV, A ;

VOLPIN, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) :671-672

[4] Novel sulfur-containing inorganic aprotic superacids as effective initiators of low-temperature cracking and isomerization of alkanes [J].

Akhrem, I ;

Gudima, S ;

Volpin, M .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (07) :812-814

[5]

AKHREM I, 1998, IN PRESS INORG CHIM

[6] Functionalization of saturated hydrocarbons by aprotic superacids .4. Ionic bromination of ethane and other alkanes and cycloalkanes with molecular bromine in the presence of systems based on polyhalomethanes and AlBr3 under mild conditions [J].

Akhrem, IS ;

Orlinkov, AV ;

Afanaseva, LV ;

Volpin, ME .

RUSSIAN CHEMICAL BULLETIN, 1996, 45 (05) :1148-1153

[7] OSMIUM LIGAND DEFICIENT CLUSTERS AS CATALYSTS FOR LIQUID-PHASE HYDROCARBON TRANSFORMATIONS [J].

AKHREM, IS ;

REZNICHENKO, SV ;

CHISTOVALOVA, NM ;

GRUSHIN, VV ;

VOLPIN, ME .

CATALYSIS LETTERS, 1993, 20 (3-4) :275-286

[8] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .3. ONE-STEP ALKYLACYLATION OF AROMATIC-HYDROCARBONS WITH ALKANES (OR CYCLOALKANES) IN THE PRESENCE OF APROTIC ORGANIC SUPERACIDS [J].

AKHREM, IS ;

ORLINKOV, AV ;

VITT, SV ;

AFANASEVA, LV ;

VOLPIN, ME .

RUSSIAN CHEMICAL BULLETIN, 1993, 42 (07) :1196-1199

[9] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS BY MEANS OF APROTIC SUPERACIDS .1. IONIC BROMINATION OF ALKANES AND CYCLOALKANES [J].

AKHREM, IS ;

ORLINKOV, AV ;

VITT, SV ;

AFANASEVA, LV ;

VOLPIN, ME .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1989, 38 (09) :1864-1868

[10] CONVERSION OF ALKANES BY THE ACTION OF ACYL HALIDES AND ALBR3 UNDER MILD CONDITIONS [J].

AKHREM, IS ;

ORLINKOV, AV ;

MYSOV, EI ;

ENALEEVA, RY ;

VOLPIN, ME .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1983, 32 (08) :1748-1748

← 1 2 3 4 5 6 7 8 9 10 →