Percolation in carbon black filled epoxy resin

被引:42
作者
Schueler, R
Petermann, J
Schulte, K
Wentzel, HP
机构
[1] UNIV DORTMUND,D-44221 DORTMUND,GERMANY
[2] DAIMLER BENZ AG,AEROSP AIRBUS,D-28183 BREMEN,GERMANY
关键词
D O I
10.1002/masy.19961040122
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The conditions to form a conductive network in carbon black filled epoxy resin were examined. It was found that the formation is controlled by particle-particle interaction which can be influenced by shear forces or by the ionic concentration of the resin. Therefore the network morphology and thus the percolation threshold depends strongly upon the processing route. On best conditions the percolation threshold was reduced to 0.06 vol.-%. That a continuous network can form with such a low volume fraction can be explained by the fractal dimension of agglomerates the network is made of.
引用
收藏
页码:261 / 268
页数:8
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