Liquid phase oxidation of cyclohexanol to adipic acid with molecular oxygen on metal catalysts

被引：31

作者：

Beziat, JC ^{[1
]}

Besson, M ^{[1
]}

Gallezot, P ^{[1
]}

机构：

[1] INST RECH CATALYSE,CNRS,F-69626 VILLEURBANNE,FRANCE

来源：

APPLIED CATALYSIS A-GENERAL | 1996年 / 135卷 / 01期

关键词：

cyclohexanol; adipic acid; oxidation; platinum catalyst; air; PLATINUM;

D O I：

10.1016/0926-860X(95)00280-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this study, a carbon supported platinum catalyst (5.4 wt.-% Pt/C) was found to be an effective heterogeneous catalyst for the liquid phase oxidation of cyclohexanol into adipic acid, The reaction was performed in water, with air as the oxidizing agent, under moderate temperature (423 K) and pressure (5 MPa air). This catalytic system achieved total conversion of the cyclohexanol and selectivities of ca. 50% in adipic acid. The main by-products were glutaric and succinic acids.

引用

页码：L7 / L11

页数：5

共 17 条

[1] CATALYTIC-OXIDATION OF GLUCOSE ON BISMUTH-PROMOTED PALLADIUM CATALYSTS [J].