Growth mechanisms and diameter evolution of single wall carbon nanotubes

被引:38
作者
Alvarez, L
Guillard, T
Sauvajol, JL
Flamant, G
Laplaze, D
机构
[1] Univ Montpellier 2, Grp Dynam Phases Condensees, F-34095 Montpellier, France
[2] Inst Sci & Genie Mat & Procedes, UPR 8521, F-66125 Font Romeu, France
关键词
D O I
10.1016/S0009-2614(01)00565-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate the growth mechanisms of single wall carbon nanotubes (SWNTs) produced by the solar method as a function of the nature of catalysts and the temperature variation in the condensing area. The Raman spectra clearly show differences in SWNT diameters induced by the change of catalyst whereas TEM pictures enhance the change of both length and diameter of the bundles. All the results are explained considering that the formation temperature range of SWNTs is the key parameter related to the target sublimation temperature and to the eutectic temperature of the binary phase diagram. (C) 2001 Elsevier Science B.V. Al rights reserved.
引用
收藏
页码:7 / 14
页数:8
相关论文
共 20 条
[1]   Solar production of single-wall carbon nanotubes: growth mechanisms studied by electron microscopy and Raman spectroscopy [J].
Alvarez, L ;
Guillard, T ;
Sauvajol, JL ;
Flamant, G ;
Laplaze, D .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2000, 70 (02) :169-173
[2]   Effect of the growth temperature on the diameter distribution and chirality of single-wall carbon nanotubes [J].
Bandow, S ;
Asaka, S ;
Saito, Y ;
Rao, AM ;
Grigorian, L ;
Richter, E ;
Eklund, PC .
PHYSICAL REVIEW LETTERS, 1998, 80 (17) :3779-3782
[3]   Production of carbon nanotubes by the solar route [J].
Guillard, T ;
Cetout, S ;
Alvarez, L ;
Sauvajol, JL ;
Anglaret, E ;
Bernier, P ;
Flamant, G ;
Laplaze, D .
EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 1999, 5 (03) :251-256
[4]  
GUILLARD T, 2000, THESIS U PERPIGNAN
[5]   Catalytic growth of single-wall carbon nanotubes from metal particles [J].
Hafner, JH ;
Bronikowski, MJ ;
Azamian, BR ;
Nikolaev, P ;
Rinzler, AG ;
Colbert, DT ;
Smith, KA ;
Smalley, RE .
CHEMICAL PHYSICS LETTERS, 1998, 296 (1-2) :195-202
[6]   Large-scale production of single-walled carbon nanotubes by the electric-arc technique [J].
Journet, C ;
Maser, WK ;
Bernier, P ;
Loiseau, A ;
delaChapelle, ML ;
Lefrant, S ;
Deniard, P ;
Lee, R ;
Fischer, JE .
NATURE, 1997, 388 (6644) :756-758
[7]   Formation mechanism of single-wall carbon nanotubes on liquid-metal particles [J].
Kanzow, H ;
Ding, A .
PHYSICAL REVIEW B, 1999, 60 (15) :11180-11186
[8]   Optical properties of single-wall carbon nanotubes [J].
Kataura, H ;
Kumazawa, Y ;
Maniwa, Y ;
Umezu, I ;
Suzuki, S ;
Ohtsuka, Y ;
Achiba, Y .
SYNTHETIC METALS, 1999, 103 (1-3) :2555-2558
[9]   Diameter control of single-walled carbon nanotubes [J].
Kataura, H ;
Kumazawa, Y ;
Maniwa, Y ;
Ohtsuka, Y ;
Sen, R ;
Suzuki, S ;
Achiba, Y .
CARBON, 2000, 38 (11-12) :1691-1697
[10]   Carbon nanotubes: The solar approach [J].
Laplaze, D ;
Bernier, P ;
Maser, WK ;
Flamant, G ;
Guillard, T ;
Loiseau, A .
CARBON, 1998, 36 (5-6) :685-688