Determination of hydrodynamic properties in highly charged colloidal systems using static and dynamic light scattering

被引:41
作者
Härtl, W [1 ]
Beck, C [1 ]
Hempelmann, R [1 ]
机构
[1] Univ Saarbrucken, D-66123 Saarbrucken, Germany
关键词
D O I
10.1063/1.478612
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structure and dynamics of highly charged colloidal silica systems has been investigated at low concentrations by means of light scattering. The index of refraction of the colloidal particles was matched using a mixture of water/glycerol. By simultaneously measuring the dynamic and static properties of the colloidal systems, we were able to extract the hydrodynamic function H(Q) at different concentrations. Our results are in excellent agreement with theoretical calculations over a large concentration range. (C) 1999 American Institute of Physics.
引用
收藏
页码:7070 / 7072
页数:3
相关论文
共 14 条
[1]  
BECK C, IN PRESS ANGEW CHEM
[2]   DIFFUSION OF SPHERES IN A CONCENTRATED SUSPENSION .2. [J].
BEENAKKER, CWJ ;
MAZUR, P .
PHYSICA A, 1984, 126 (03) :349-370
[3]   SHORT-TIME DIFFUSION-COEFFICIENTS AND HIGH-FREQUENCY VISCOSITY OF DILUTE SUSPENSIONS OF SPHERICAL BROWNIAN PARTICLES [J].
CICHOCKI, B ;
FELDERHOF, BU .
JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (02) :1049-1054
[4]   STRUCTURAL EFFECTS OF POLYDISPERSITY IN CHARGED COLLOIDAL DISPERSIONS [J].
DAGUANNO, B ;
KLEIN, R .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (03) :379-390
[5]   A RESCALED MSA STRUCTURE FACTOR FOR DILUTE CHARGED COLLOIDAL DISPERSIONS [J].
HANSEN, JP ;
HAYTER, JB .
MOLECULAR PHYSICS, 1982, 46 (03) :651-656
[6]  
HARTL W, 1995, J CHEM PHYS, V102, P6613, DOI 10.1063/1.469377
[7]  
Hartl W, 1996, J CHEM PHYS, V105, P9625, DOI 10.1063/1.472793
[8]  
Klein R., 1996, LIGHT SCATTERING PRI
[9]   Influence of hydrodynamic interactions on long-time diffusion in charge-stabilized colloids [J].
Nagele, G ;
Baur, P .
EUROPHYSICS LETTERS, 1997, 38 (07) :557-562
[10]   Long-time dynamics of charged colloidal suspensions: hydrodynamic interaction effects [J].
Nagele, G ;
Baur, P .
PHYSICA A, 1997, 245 (3-4) :297-336