Preparation and Evaluation of Graphite Oxide Reduced at 220 °C

被引:197
作者
Zangmeister, Christopher D. [1 ]
机构
[1] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA
关键词
GRAPHENE OXIDE; REDUCTION; FILMS; TRANSPARENT; ENVIRONMENT; SERIES;
D O I
10.1021/cm102005m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reduction of graphite oxide (GO) thin films was evaluated at 220 degrees C using a combination of infrared (FTIR) and X-ray photoemission spectroscopies (XPS). The results were correlated with electrical resistance measurements. The chemical composition of GO was C-8(OH)(3)O-0.8 and reduced to C-8(OH)(0.5)O-0.3 after nearly 24 h of low-temperature processing, defined as 220 degrees C. The sheet resistance of dropcast GO thin films processed at 220 degrees C in air was 8 k Omega sq(-1), similar to GO reduced at >800 degrees C in an inert atmosphere.
引用
收藏
页码:5625 / 5629
页数:5
相关论文
共 34 条
[1]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[2]   Modeling of graphite oxide [J].
Boukhvalov, D. W. ;
Katsnelson, M. I. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (32) :10697-10701
[3]   Langmuir-Blodgett Assembly of Graphite Oxide Single Layers [J].
Cote, Laura J. ;
Kim, Franklin ;
Huang, Jiaxing .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (03) :1043-1049
[4]   Preparation and characterization of graphene oxide paper [J].
Dikin, Dmitriy A. ;
Stankovich, Sasha ;
Zimney, Eric J. ;
Piner, Richard D. ;
Dommett, Geoffrey H. B. ;
Evmenenko, Guennadi ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
NATURE, 2007, 448 (7152) :457-460
[5]   The chemistry of graphene oxide [J].
Dreyer, Daniel R. ;
Park, Sungjin ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240
[6]   Environment-Friendly Method To Produce Graphene That Employs Vitamin C and Amino Acid [J].
Gao, Jian ;
Liu, Fang ;
Liu, Yiliu ;
Ma, Ning ;
Wang, Zhiqiang ;
Zhang, Xi .
CHEMISTRY OF MATERIALS, 2010, 22 (07) :2213-2218
[7]   Hydrazine and Thermal Reduction of Graphene Oxide: Reaction Mechanisms, Product Structures, and Reaction Design [J].
Gao, Xingfa ;
Jang, Joonkyung ;
Nagase, Shigeru .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (02) :832-842
[8]   A chemical route to graphene for device applications [J].
Gilje, Scott ;
Han, Song ;
Wang, Minsheng ;
Wang, Kang L. ;
Kaner, Richard B. .
NANO LETTERS, 2007, 7 (11) :3394-3398
[9]   A new structural model for graphite oxide [J].
He, HY ;
Klinowski, J ;
Forster, M ;
Lerf, A .
CHEMICAL PHYSICS LETTERS, 1998, 287 (1-2) :53-56
[10]   STUDY OF OXYGEN-CONTAINING GROUPS IN A SERIES OF GRAPHITE OXIDES - PHYSICAL AND CHEMICAL CHARACTERIZATION [J].
HONTORIALUCAS, C ;
LOPEZPEINADO, AJ ;
LOPEZGONZALEZ, JDD ;
ROJASCERVANTES, ML ;
MARTINARANDA, RM .
CARBON, 1995, 33 (11) :1585-1592