A lanthanide phosphinidene complex: Synthesis, structure, and phospha-Wittig reactivity

被引：133

作者：

Masuda, Jason D. ^{[1
]}

Jantunen, Kimberly C. ^{[1
]}

Ozerov, Oleg V. ^{[2
]}

Noonan, Kevin J. T. ^{[3
]}

Gates, Derek P. ^{[3
]}

Scott, Brian L. ^{[1
]}

Kiplinger, Jaqueline L. ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

[2] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA

[3] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 08期

关键词：

D O I：

10.1021/ja7105306

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first lanthanide complex featuring a phosphinidene functional group has been prepared and isolated. Preliminary reactivity studies demonstrate that the lutetium(III) phosphinidene complex, [{2((Pr2P)-Pr-t)-4-Me-C6H3)(2)NLu](2)(mu-PMes)(2), behaves as a phospha-Wittig reagent with aldehydes and ketones to give the corresponding phosphaalkenes. Attempts to use the bulky phosphine H2P-2,4,6-Bu-t(3)-C6H2 to kinetically stabilize a terminal phosphinidene resulted in C-H activation of an ortho-Bu-t group and formation of a phosphaindole.

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页码：2408 / 2409

页数：2

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