A 2-styrylboronate ester

被引：6

作者：

Clegg, W

Marder, TB

Scott, AJ

Wiesauer, C

Weissensteiner, W

机构：

[1] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[2] Univ Durham, Dept Chem, Durham DH1 3LE, England

[3] Univ Waterloo, Dept Chem, Waterloo, ON N2L 3G1, Canada

[4] Univ Vienna, Inst Organ Chem, A-1090 Vienna, Austria

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536800019097

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Molecules of the title compound, (E)-2-(2-phenylethenyl)-1,3,2-benzodioxaborole, C14H11BO2, are essentially completely planar with a high degree of conjugation. They pack with a herring-bone pattern in the crystal structure. The compound is synthesized with high regioselectivity by hydroboration of phenylacetylene with catecholborane.

引用

收藏

页码：O63 / O65

页数：3

相关论文

共 17 条

[1]

ALLEN FH, 1992, INT TABLES CRYSTALLO, VC, P685

[2] CATECHOLBORANE (1,3,2-BENZODIOXABOROLE) AS A NEW, GENERAL MONOHYDROBORATION REAGENT FOR ALKYNES - CONVENIENT SYNTHESIS OF ALKENEBORONIC ESTERS AND ACIDS FROM ALKYNES VIA HYDROBORATION [J].

BROWN, HC ;

GUPTA, SK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (12) :4370-&

[3] HYDROBORATION .39. 1,3,2-BENZODIOXABOROLE (CATECHOLBORANE) AS A NEW HYDROBORATION REAGENT FOR ALKENES AND ALKYNES - GENERAL SYNTHESIS OF ALKANEBORONIC AND ALKENEBORONIC ACIDS AND ESTERS VIA HYDROBORATION - DIRECTIVE EFFECTS IN HYDROBORATION OF ALKENES AND ALKYNES WITH CATECHOLBORANE [J].

BROWN, HC ;

GUPTA, SK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (18) :5249-5255

[4] HYDROBORATION .65. RELATIVE REACTIVITIES OF REPRESENTATIVE ALKENES AND ALKYNES TOWARD HYDROBORATION BY CATECHOLBORANE [J].

BROWN, HC ;

CHANDRASEKHARAN, J .

JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (25) :5080-5082

[5] The products of catalysed diboration of bis(p-tolyl)ethyne and of 4-cyanophenyl-ethyne by bis(catecholato-O,O')diboron [J].

Clegg, W ;

Scott, AJ ;

Lesley, G ;

Marder, TB ;

Norman, NC .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :1991-1995

[6] CHLOROBORATION AND ALLIED REACTIONS OF UNSATURATED COMPOUNDS .V. HALOBORATION AND PHENYLBORATION OF OLEFINS - AND PREPARATION OF HEXAPHENYL-1,4-DIBORACYCLOHEXA-2,5-DIENE [J].

JOY, F ;

LAPPERT, MF ;

PROKAI, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1966, 5 (06) :506-&

[7] CATECHOLBORANE - NEW HYDROBORATION REAGENT [J].

LANE, CF ;

KABALKA, GW .

TETRAHEDRON, 1976, 32 (09) :981-990

[8] REACTION OF 2-ALKENYL-1,3,2-BENZODIOXABOROLES WITH MERCURIC ACETATE - CONVENIENT STEREOSPECIFIC PROCEDURE FOR CONVERSION OF ALKYNES INTO ALKENYLMERCURIC SALTS [J].

LAROCK, RC ;

GUPTA, SK ;

BROWN, HC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (12) :4371-&

[9] Synthesis and characterization of platinum(II)-bis(boryl) catalyst precursors for diboration of alkynes and diynes: Molecular structures of cis-[(PPh(3))(2)Pt(B-4-Bu(t)cat)(2)], cis-[(PPh(3))(2)Pt(Bcat)(2)], cis-[(dppe)Pt(Bcat)(2)], cis-[(dppb)Pt(Bcat)(2)], (E)-(4-MeOC(6)H(4))C(Bcat)=CH(Bcat), (Z)-(C6H5)C(Bcat)=C(C6H5)(Bcat), and (Z,Z)-(4-MeOC(6)H(4))C(Bcat)=C(Bcat)C(Bcat)=C(4-MeOC(6)H(4))(Bcat) (cat equals 1,2-O2C6H4; dppe equals Ph(2)PCH(2)CH(2)PPh(2); dppb equals Ph(2)P(CH2)(4)PPh(2)) [J].

Lesley, G ;

Nguyen, P ;

Taylor, NJ ;

Marder, TB ;

Scott, AJ ;

Clegg, W ;

Norman, NC .

ORGANOMETALLICS, 1996, 15 (24) :5137-5154

[10] A test of crystal structure prediction of small organic molecules [J].

Lommerse, JPM ;

Motherwell, WDS ;

Ammon, HL ;

Dunitz, JD ;

Gavezzotti, A ;

Hofmann, DWM ;

Leusen, FJJ ;

Mooij, WTM ;

Price, SL ;

Schweizer, B ;

Schmidt, MU ;

van Eijck, BP ;

Verwer, P ;

Williams, DE .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2000, 56 (04) :697-714