Reduction of tris(benzene-1,2-dithiolate) molybdenum(VI) by hydroxide ions in dry tetrahydrofuran solution

被引：6

作者：

Cervilla, A

Pérez-Pla, F

Llopis, E

机构：

[1] ICMUV, Dept Quim Inorgan, Valencia, Spain

[2] Univ Valencia, Dept Quim Fis, E-46100 Valencia, Spain

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 22期

关键词：

D O I：

10.1039/b106123m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tris(benzene-1,2-dithiolate)molybdenum(VI) reacts rapidly and quantitatively with tetrabutylammonium hydroxide to yield the corresponding Mo(V) and Mo(IV) complexes and hydrogen peroxide; the reaction has been executed in dry tetrahydrofuran where the reaction rate shows a fair dependence on complex and OH- concentrations.

引用

页码：2332 / 2333

页数：2

共 10 条

[1]

BURNS RP, 1979, ADV INORG CHEM, V22, P303

[2]

CERVILLA A, IN PRESS INORG CHEM

[3] The structure and mode of action of the cofactor of the oxomolybdoenzymes [J].

Collison, D ;

Garner, CD ;

Joule, JA .

CHEMICAL SOCIETY REVIEWS, 1996, 25 (01) :25-+

[4] SYNTHESIS, CYCLIC VOLTAMMETRIC AND ELECTROSPRAY MASS-SPECTROMETRIC STUDIES OF A SERIES OF TRIS-SUBSTITUTED 1,2-DITHIOLENE COMPLEXES OF TUNGSTEN AND MOLYBDENUM [J].

FALARAS, P ;

MITSOPOULOU, CA ;

ARGYROPOULOS, D ;

LYRIS, E ;

PSAROUDAKIS, N ;

VRACHNOU, E ;

KATAKIS, D .

INORGANIC CHEMISTRY, 1995, 34 (18) :4536-4542

[5]

GANS P, 1992, DATA FITTING CHEM SC, pCH8

[6] ELECTRON-TRANSFER REACTIONS AND NATURE OF SOLVENT EFFECT ON TRIS-TOLUENE-3,4-DITHIOLATES OF RHENIUM, TUNGSTEN, MOLYBDENUM AND TECHNETIUM [J].

KAWASHIMA, M ;

KOYAMA, M ;

FUJINAGA, T .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1976, 38 (04) :801-805

[7]

McCleverty J. A., 1968, PROG INORG CHEM, V10, P49, DOI DOI 10.1002/9780470166116.CH2

[8]

MCCLEVERTY JA, 1994, ENCY INORGANIC CHEM, P2304

[9] A new algorithm for the kinetic data analysis [J].

Pérez Pla, F.F. ;

Bea Redón, J.F. ;

Valero, R. .

2000, Elsevier (53) :1-2

[10]

SELLMANN D, 1985, Z NATURFORSCH B, V40, P380

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