Vanadium haloperoxidases

被引：107

作者：

Butler, A ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA

来源：

CURRENT OPINION IN CHEMICAL BIOLOGY | 1998年 / 2卷 / 02期

基金：

美国海洋和大气管理局; 美国国家科学基金会;

关键词：

D O I：

10.1016/S1367-5931(98)80070-7

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The nature of the oxidized halogen intermediate in vanadium bromoperoxidase has recently been shown to depend on the nature of the organic substrate. For example, in the presence of indoles, vanadium bromoperoxidase does not release a freely diffusible oxidized halogen intermediate (such as HOBr+/-BR2+/-Br-3(-)). Regioselective investigations are, therefore, now feasible.

引用

页码：279 / 285

页数：7

共 40 条

[1] VANADIUM K-EDGE X-RAY ABSORPTION-SPECTROSCOPY OF BROMOPEROXIDASE FROM ASCOPHYLLUM-NODOSUM [J].

ARBER, JM ;

DEBOER, E ;

GARNER, CD ;

HASNAIN, SS ;

WEVER, R .

BIOCHEMISTRY, 1989, 28 (19) :7968-7973

[2] SYNTHESIS, CHARACTERIZATION AND PHYSICOCHEMICAL PROPERTIES OF PEROXO-VANADIUM(V) COMPLEXES WITH GLYCINE AS THE HETEROLIGAND [J].

BHATTACHARJEE, M ;

CHAUDHURI, MK ;

ISLAM, NS ;

PAUL, PC .

INORGANICA CHIMICA ACTA, 1990, 169 (01) :97-100

[3]

Butler A, 1997, STRUCT BOND, V89, P109

[4]

BUTLER A, 1997, COMPREHENSIVE BIOL C, V4, P1

[5]

BUTLER A, 1997, P ROY NETHERLANDS AC, P55

[6]

BUTLER A, 1995, ACS SYM SER, P329

[7]

BUTLR A, 1998, BIOINORGANIC CATALYS

[8] BIOMIMICS OF VANADIUM BROMOPEROXIDASE - VANADIUM(V)-SCHIFF BASE-CATALYZED OXIDATION OF BROMIDE BY HYDROGEN-PEROXIDE [J].

CLAGUE, MJ ;

KEDER, NL ;

BUTLER, A .

INORGANIC CHEMISTRY, 1993, 32 (22) :4754-4761

[9] ON THE MECHANISM OF CIS-DIOXOVANADIUM(V)-CATALYZED OXIDATION OF BROMIDE BY HYDROGEN-PEROXIDE - EVIDENCE FOR A REACTIVE, BINUCLEAR VANADIUM(V) PEROXO COMPLEX [J].

CLAGUE, MJ ;

BUTLER, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (12) :3475-3484

[10]

CLSI S, 1974, J CHEM SOC DA, P793

← 1 2 3 4 →