Electrosynthesis and oxidation of new oligoazomethines containing N-ethylcarbazole groups

被引：15

作者：

Chevrot, C ^{[1
]}

Henri, T ^{[1
]}

机构：

[1] Univ Cergy Pontoise, Lab Polymeres & Mat Electroactifs, Equipe React Interfaces, EA 2528, F-95031 Cergy Pontoise, France

来源：

SYNTHETIC METALS | 2001年 / 118卷 / 1-3期

关键词：

electrosynthesis; oligo and polyazomethines; Schiff bust polymers; N-alkylcarbazole; chemical doping; conjugated polymers; charge transfer transition;

D O I：

10.1016/S0379-6779(00)00403-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Oligoazomethines containing the N-ethylcarbazole group have been synthesized by dehalogenative polycondensation of dibromides of N-ethylcarbazole-azomethine as monomer in the presence of electrogenerated zerovalent nickel acting as a catalyst. Chemical oxidation of these new compounds by FeCl3 was studied by optical spectroscopy and electrochemical oxidation by cyclic voltammetry. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：157 / 166

页数：10

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