Kinetics of the dissociation of transition metal complexes with α,α-dipyrrolylmethene in acetic acid-benzene as a binary proton-donating solvent

被引：13

作者：

Guseva, GB ^{[1
]}

Antina, EV ^{[1
]}

Berezin, NB ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Solut Chem, Ivanovo 153045, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 10期

关键词：

Acetic; Physical Chemistry; Benzene; Acetic Acid; Kinetic Parameter;

D O I：

10.1023/A:1026067915376

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The kinetics of the dissociation of Co(II), Ni(II). and Zn(II) complexes with 4,4'-dibutyl-3,3',5,5'-tetramethyldipyrrol-2,2'-ylmethene was studied in acetic acid-benzene as a binary proton-donating solvent. The metal nature was found to affect the kinetic parameters of the process. Assumptions were made about the limiting step of the process and the effectiveness of d metal ions in the template synthesis of porphyrins from dipyrrolylmethenes.

引用

页码：690 / 693

页数：4

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