Slow Relaxation of the Magnetization in a 4,2-Wavelike Fe2IIICoII Heterobimetallic Chain

被引：33

作者：

Marilena Toma, Luminita ^{[1
]}

Ruiz-Perez, Catalina ^{[2
]}

Lloret, Francesc ^{[1
]}

Julve, Miguel ^{[1
]}

机构：

[1] Univ Valencia, Dept Quim Inorgan, Inst Ciencia Mol, Fac Quim, Valencia 46980, Spain

[2] Univ La Laguna, Dept Fis Fundamental 2, Fac Fis, Lab Rayos & Mat Mol X, Tenerife 38204, Spain

来源：

INORGANIC CHEMISTRY | 2012年 / 51卷 / 03期

关键词：

SPIN-CROSSOVER; MAGNETS; NETWORKS; COMPLEX; LIGAND;

D O I：

10.1021/ic202410t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the low-spin iron(III) complex [Fe(dmbpy)(CN)(4)](-) (1) with fully solvated cobalt(II) ions affords the cyanide-bridged heterobimetallic chain {[Fe-III(dmbpy)(CN)(4)](2)Co-II(H2O)(2)}(n)center dot 4nH(2)O (2), which exhibits intrachain ferromagnetic coupling and double slow relaxation of the magnetization.

引用

页码：1216 / 1218

页数：3

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