Synthesis of novel magnetic polymer microspheres with amphiphilic structure

被引:20
作者
Liu, XY
Ding, XB
Zheng, ZH
Peng, YX [1 ]
Long, XP
Wang, XC
Chan, ASC
Yip, CW
机构
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
[2] China Acad Engn Phys, Inst Chem Mat, Shichuan Mianyang 621900, Peoples R China
[3] Hong Kong Polytech Univ, Open Lab Chirotechnol, Hong Kong, Hong Kong, Peoples R China
[4] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China
关键词
amphiphilic; magnetic; microsphere;
D O I
10.1002/app.12860
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Novel magnetic polymer microspheres with amphiphilic structure ranging in diameter from 5 to 80 mum were prepared by dispersion copolymerization of styrene and poly(ethylene oxide) acrylamide macromonomer (MPEO) in the presence of Fe3O4 magnetic fluid. The effects of various polymerization parameters on the average particle size were systematically investigated. The average particle size was found to increase with increasing initiator concentration. It also increased with decreasing stabilizer concentration and MPEO concentration. The content of the amino groups localized in the microspheres ranged from 0.01 to 0.25 mmol/g. (C) 2003 Wiley Periodicals, Inc.
引用
收藏
页码:1879 / 1884
页数:6
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