Influence of an electron-deficient bridging o-carborane on the electronic properties of an [FeFe] hydrogenase active site model

被引：61

作者：

Schwartz, Lennart ^{[2
]}

Eriksson, Lars ^{[3
]}

Lomoth, Reiner ^{[2
]}

Teixidor, Francesc ^{[1
]}

Vinas, Clara ^{[1
]}

Ott, Sascha ^{[2
]}

机构：

[1] CSIC, Inst Ciencia Mat, Barcelona 08193, Spain

[2] Uppsala Univ, Dept Photochem & Mol Sci, Angstrom Lab, S-75120 Uppsala, Sweden

[3] Stockholm Univ, Arrhenius Lab, Div Struct Chem, S-10691 Stockholm, Sweden

来源：

DALTON TRANSACTIONS | 2008年 / 18期

关键词：

D O I：

10.1039/b802908n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The IR carbonyl stretching frequencies of [Fe-2(SRS)(CO)(6)] complexes correlate well with their first reduction potential; an [FeFe] hydrogenase model with a very mild reduction potential has been realized by using a strongly electron deficient carborane-dithiolate bridge.

引用

页码：2379 / 2381

页数：3

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