Electropolymerization of an immiscible monomer in aqueous electrolytes using acoustic emulsification

被引：43

作者：

Asami, R ^{[1
]}

Atobe, M ^{[1
]}

Fuchigami, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Yokohama, Kanagawa 2268502, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 38期

关键词：

D O I：

10.1021/ja0546931

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper reports on the novel electropolymerization of an immiscible monomer, such as 3,4-ethylenedioxythiophene (EDOT), in aqueous electrolytes using acoustic emulsification. This new methodology has many practical advantages and characteristics: (a) the formation of stable monomer droplets in aqueous electrolytes without added surfactants using ultrasonic treatment; (b) very smooth electropolymerization in aqueous electrolytes via the direct electron transfer between the electrode and the immiscible monomer droplets; (c) good conductivity after doping of the polymer film formed. Copyright © 2005 American Chemical Society.

引用

页码：13160 / 13161

页数：2

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