A new rhodium(III) complex with a tripodal bis(imidazolylidene) ligand.: Synthesis and catalytic properties

被引：92

作者：

Mas-Marzá, E

Poyatos, M

Sanaú, M

Peris, E

机构：

[1] Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, Spain

[2] Univ Valencia, Dept Quim Inorgan, Burjassot 46100, Spain

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 03期

关键词：

D O I：

10.1021/om0341552

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new bis(imidazolylidene) tripodal ligand has been obtained by a simple method. The coordination of this ligand to Rh provides the first Rh(III) complex with a bis(carbene) ligand in a tripodal coordination, and its catalytic properties toward hydrogen transfer have been examined.

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页码：323 / 325

页数：3

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