Influence of lattice integrity and phase composition on the photocatalytic hydrogen production efficiency of ZnS nanomaterials

被引：75

作者：

Hong, Yangping ^{[2
]}

Zhang, Jun ^{[1
]}

Wang, Xian ^{[2
]}

Wang, Yongjing ^{[2
]}

Lin, Zhang ^{[2
]}

Yu, Jiaguo ^{[1
]}

Huang, Feng ^{[2
]}

机构：

[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China

[2] Chinese Acad Sci, Key Lab Optoelect Mat Chem & Phys, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

来源：

NANOSCALE | 2012年 / 4卷 / 09期

基金：

中国国家自然科学基金;

关键词：

VISIBLE-LIGHT IRRADIATION; H-2; EVOLUTION; SOLID-SOLUTION; AQUEOUS-SOLUTIONS; SULFIDE; WATER; CDS; NANOSTRUCTURE; GENERATION; NANOSHEETS;

D O I：

10.1039/c2nr30150d

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Ambient S annealing was adopted to regulate the crystallinity of a ZnS microsphere, which resulted in a significant improvement in the photocatalytic hydrogen production activity (PHPA). Moreover, with S ambient treatment, wurtzite ZnS showed better PHPA than sphalerite ZnS, possibly because the inter-polar electric field of the wurtzite phase could promote the separation of photo-excited electron-hole pairs.

引用

收藏

页码：2859 / 2862

页数：4

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