Very large ising-type magnetic anisotropy in a mononuclear NiII complex

被引：105

作者：

Rogez, G

Rebilly, JN

Barra, AL

Sorace, L

Blondin, G

Kirchner, N

Duran, M

van Slageren, J

Parsons, S

Ricard, L

Marvilliers, A

Mallah, T

机构：

[1] Univ Paris 11, UMR CNRS 8613, Chim Inorgan Lab, F-91405 Orsay, France

[2] CNRS, UMR 7504, IPCMS GMI, F-67034 Strasbourg, France

[3] CNRS, UPR 5021, Lab Champs Magnet Intenses, F-38042 Grenoble, France

[4] Univ Florence, UdR INSTM, I-50019 Sesto Fiorentino, Italy

[5] Univ Florence, Dept Chem, I-50019 Sesto Fiorentino, Italy

[6] Univ Stuttgart, Inst Phys 1, D-70550 Stuttgart, Germany

[7] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[8] Ecole Polytech, UMR CNRS 7653, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 12期

关键词：

angular-overlap model; EPR spectroscopy; FDMR spectroscopy; magnetic properties; nickel;

D O I：

10.1002/anie.200462294

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Complementarity between different techniques (magnetization, HF-HFEPR, FDMRS) and angular-overlap-model calculations allow the precise determination of the spin-Hamiltonian parameters in an isolated octahedral NiII complex (see structure), which exhibits the largest easy axis magnetic anisotropy reported to date (D = -10.1 cm-1, E/|D| = 0.02). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1876 / 1879

页数：4

共 36 条

[1]

Abbati GL, 2001, CHEM-EUR J, V7, P1796, DOI 10.1002/1521-3765(20010417)7:8<1796::AID-CHEM17960>3.0.CO

[2]

2-Y

[3]

AJIRO Y, 1975, PHYS REV B, V12, P39, DOI 10.1103/PhysRevB.12.39

[4]

ALTOMARE A, SIR97 INTEGRATED PAC, P101