Quantum effects in the structure of liquid benzene at room temperature

被引:6
作者
Benmore, CJ
Tomberli, B
Egelstaff, PA
Neuefeind, J
机构
[1] Argonne Natl Lab, IPNS, Argonne, IL 60439 USA
[2] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England
[3] Univ Guelph, Dept Phys, Guelph, ON N1G 2W1, Canada
[4] DESY, HASYLAB, D-22603 Hamburg, Germany
基金
加拿大自然科学与工程研究理事会;
关键词
D O I
10.1080/00268970010018404
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Structural differences between liquid light (protonated) benzene and heavy (deuterated) benzene at room temperature have been measured using high energy electromagnetic radiation scattering techniques. Intra- and intermolecular effects have been examined, and the main quantum contribution is shown to be intramolecular. This is in contrast to the quantum-effects measured in liquid water at room temperature, which are primarily intermolecular.
引用
收藏
页码:787 / 794
页数:8
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