Supramolecular cation of an acyclic polyether: potassium(pentaethylene glycol) in a molecular conducting nickel dithiolate salt

被引：24

作者：

Akutagawa, T ^{[1
]}

Nezu, Y

Hasegawa, T

Sugiura, K

Nakamura, T

Inabe, T

Sakata, Y

Underhill, AE

机构：

[1] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0600812, Japan

[2] Hokkaido Univ, Grad Sch Environm Earth Sci, Sapporo, Hokkaido 0600810, Japan

[3] Hokkaido Univ, Fac Sci, Dept Chem, Sapporo, Hokkaido 0600810, Japan

[4] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan

[5] Univ Wales, Dept Chem, Bangor LL57 3UW, Gwynedd, Wales

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 23期

关键词：

D O I：

10.1039/a807474g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray structural analysis of the title compound revealed the formation of segregated [Ni(dmit)(2)] (dmit = 2-thioxo-1,3-dithiol-4,5-dithiolate) columns and dimeric K-2(+)[PEG]2 (PEG = pentaethylene glycol) supramolecular cations in the crystal; the interaction between K+ and acyclic PEG was found to be weaker that that between K+ and cyclic polyether 18-crown-6.

引用

页码：2599 / 2600

页数：2

共 11 条

[1]

Akutagawa T., 1997, SYNTHETIC MET, V86, P1961

[2]

AKUTAGAWA T, 1996, J MATER CHEM, V7, P135

[3]

AKUTAGAWA T, UNPUB

[4] VAN DER WAALS VOLUMES + RADII [J].