Icelike water monolayer adsorbed on mica at room temperature

被引：295

作者：

Miranda, PB ^{[1
]}

Xu, L

Shen, YR

Salmeron, M

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA

来源：

PHYSICAL REVIEW LETTERS | 1998年 / 81卷 / 26期

关键词：

D O I：

10.1103/PhysRevLett.81.5876

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The structure of a water film formed on mica at room temperature, in equilibrium with water vapor at various relative humidities (RH), was studied using sum-frequency-generation (SFG) vibrational spectroscopy and scanning polarization force microscopy (SPFM). Analysis of the O-D stretch modes in the SFG spectra of D2O on mica indicates that as RH increases, the submonolayer water structure evolves into a more ordered hydrogen-bonding network. At full monolayer coverage (similar to 90% RH), the SFG spectrum suggests an icelike film with no dangling O-D groups, in agreement with a recent molecular dynamics simulation.

引用

页码：5876 / 5879

页数：4

共 23 条

[1]

ADAMSON AW, 1990, PHYSICAL CHEM SURFAC

[2] VAPOR ADSORPTION ON MICA AND SILICON - ENTROPY EFFECTS, LAYERING, AND SURFACE FORCES [J].

BEAGLEHOLE, D ;

CHRISTENSON, HK .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (08) :3395-3403

[3] OH STRETCHING REGION INFRARED-SPECTRA OF LOW-DENSITY AMORPHOUS SOLID WATER AND POLYCRYSTALLINE ICE IH [J].

BERGREN, MS ;

SCHUH, D ;

SCEATS, MG ;

RICE, SA .

JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (08) :3477-3482

[4] STRUCTURAL COMPONENT OF DISJOINING PRESSURE [J].

DERJAGUIN, BV ;

CHURAEV, NV .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1974, 49 (02) :249-255

[5] SURFACE VIBRATIONAL SPECTROSCOPIC STUDIES OF HYDROGEN-BONDING AND HYDROPHOBICITY [J].

DU, Q ;

FREYSZ, E ;

SHEN, YR .

SCIENCE, 1994, 264 (5160) :826-828

[6] VIBRATIONAL SPECTROSCOPY OF WATER AT THE VAPOR WATER INTERFACE [J].

DU, Q ;

SUPERFINE, R ;

FREYSZ, E ;

SHEN, YR .

PHYSICAL REVIEW LETTERS, 1993, 70 (15) :2313-2316

[7] D2O ice on controlled wettability self-assembled alkanethiolate monolayers: Cluster formation and substrate-adsorbate interaction [J].

Engquist, I ;

Liedberg, B .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (51) :20089-20096

[8] SCANNING POLARIZATION FORCE MICROSCOPY - A TECHNIQUE FOR IMAGING LIQUIDS AND WEAKLY ADSORBED LAYERS [J].

HU, J ;

XIAO, XD ;

SALMERON, M .

APPLIED PHYSICS LETTERS, 1995, 67 (04) :476-478

[9] IMAGING THE CONDENSATION AND EVAPORATION OF MOLECULARLY THIN-FILMS OF WATER WITH NANOMETER RESOLUTION [J].

HU, J ;

XIAO, XD ;

OGLETREE, DF ;

SALMERON, M .

SCIENCE, 1995, 268 (5208) :267-269

[10] Interaction of water with a fatty acid Langmuir film [J].

Miranda, PB ;

Du, Q ;

Shen, YR .

CHEMICAL PHYSICS LETTERS, 1998, 286 (1-2) :1-8

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