A facile synthesis of 1,3,5-triaryl benzenes from acetophenone diethyl ketals in the presence of acetyl chloride and SmCl3

被引：15

作者：

Cheng, KJ ^{[1
]}

Ding, ZB ^{[1
]}

Wu, SH ^{[1
]}

机构：

[1] FUDAN UNIV,DEPT CHEM,SHANGHAI 200433,PEOPLES R CHINA

来源：

SYNTHETIC COMMUNICATIONS | 1997年 / 27卷 / 01期

关键词：

D O I：

10.1080/00397919708004800

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Samarium trichloride, SmCl3, has been found to be an efficient catalyst for the synthesis of 1,3,5-triaryl benzenes from acetophenone diethyl ketals in the presence of acetyl chloride under solvent of pentane and mild conditions.

引用

页码：11 / 15

页数：5

共 18 条

[1]

ASLAM M, Patent No. 9314065

[2]

AUDOUY R, 1989, TETRAHEDRON, V45, P2067

[3]

GARLASCHELLI L, 1990, TETRAHEDRON LETT, V31, P5818

[4]

LINDEMAN SV, 1994, IZU AKAD NAUK K, P1986

[5]

LUCHE JL, 1981, J AM CHEM SOC, V103, P5454

[6] YB(CN)3-CATALYZED REACTION OF AZIRIDINES WITH CYANOTRIMETHYLSILANE - A FACILE SYNTHESIS OF OPTICALLY PURE BETA-AMINO NITRILES [J].

MATSUBARA, S ;

KODAMA, T ;

UTIMOTO, K .

TETRAHEDRON LETTERS, 1990, 31 (44) :6379-6380

[7] REACTION OF CYANOTRIMETHYLSILANE WITH OXIRANES UNDER YB(CN)3 CATALYSIS [J].

MATSUBARA, S ;

ONISHI, H ;

UTIMOTO, K .

TETRAHEDRON LETTERS, 1990, 31 (43) :6209-6212

[8] TRICHLOROLANTHANOID(LNCL3)-CATALYZED FRIEDEL-CRAFTS ALKYLATION REACTIONS [J].

MINE, N ;

FUJIWARA, Y ;

TANIGUCHI, H .

CHEMISTRY LETTERS, 1986, (03) :357-360

[9] APPLICATION OF LANTHANIDE REAGENTS IN ORGANIC-SYNTHESIS [J].

MOLANDER, GA .

CHEMICAL REVIEWS, 1992, 92 (01) :29-68

[10] AROMATIC SUBSTITUTION .30. FRIEDEL-CRAFTS BENZYLATION OF BENZENE AND TOLUENE WITH BENZYL AND SUBSTITUTED BENZYL HALIDES [J].

OLAH, GA ;

KOBAYASHI, S ;

TASHIRO, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (21) :7448-+

← 1 2 →