Dielectric properties of alcohols (C1-C5) at 2450 MHz and 915 MHz

被引:21
作者
Liao, XJ
Raghavan, GSV
Yaylayan, VA
机构
[1] McGill Univ, Dept Agr & Biosyst Engn, St Anne De Bellevue, PQ H9X 3V9, Canada
[2] McGill Univ, Dept Food Sci & Agr Chem, St Anne De Bellevue, PQ H9X 3V9, Canada
关键词
D O I
10.1016/S0167-7322(01)00241-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dielectric properties of alcohols (C-1-C-5) at 2450 MHz and 915 MHz were measured at different temperatures using a cavity perturbation technique. Dielectric properties were shown to be dependent on temperature, frequency and alcohol type. The dielectric constants increased with temperature at both frequencies; however, there were significant differences in dielectric loss factor. Linear and quadratic equations were developed for each type of alcohol to relate changes in dielectric constant, dielectric loss factor or half power-penetration depth with temperature. These relationships are useful in estimating the volumetric heating of alcohols by microwave energy at 2450 MHz or 915 MHz, analyzing the differentially thermal transition in materials, selecting solvents and shedding some light on microwave-assisted chemical reactions. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:51 / 60
页数:10
相关论文
共 20 条
[1]   Hetero-Diels-Alder reactions of homochiral 1,2-diaza-1,3-butadienes with diethyl azodicarboxylate under microwave irradiation.: Theoretical rationale of the stereochemical outcome [J].
Avalos, M ;
Babiano, R ;
Cintas, P ;
Clemente, FR ;
Jiménez, JL ;
Palacios, JC ;
Sánchez, JB .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (17) :6297-6305
[2]   MULTIPLE REFLECTION TIME DOMAIN METHOD IN DIELECTRIC-SPECTROSCOPY - APPLICATION TO STUDY OF SOME NORMAL PRIMARY ALCOHOLS [J].
BOTTREAU, AM ;
DUTUIT, Y ;
MOREAU, J .
JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (08) :3331-3336
[3]   Application of focused microwaves to the scale-up of solvent-free organic reactions [J].
Cléophax, J ;
Liagre, M ;
Loupy, A ;
Petit, A .
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2000, 4 (06) :498-504
[4]  
COPSON DA, 1975, MICROWAVE HEATING
[5]   DIELECTRIC PROPERTIES OF LIQUID BUTYL ALCOHOLS [J].
DANNHAUSER, W ;
COLE, RH .
JOURNAL OF CHEMICAL PHYSICS, 1955, 23 (10) :1762-1766
[6]  
Decareau R. V., 1992, MICROWAVE FOODS NEW
[7]  
DOUGLAS HE, 1987, REPORT CTR DEV TECHN, P33
[8]   Dielectric parameters relevant to microwave dielectric heating [J].
Gabriel, C ;
Gabriel, S ;
Grant, EH ;
Halstead, BSJ ;
Mingos, DMP .
CHEMICAL SOCIETY REVIEWS, 1998, 27 (03) :213-223
[9]  
GHAHINE R, 1976, J CHEM PHYS, V645, P2211
[10]   DIELECTRIC PROPERTIES OF FORMAMIDE, ETHANEDIOL AND METHANOL [J].
JORDAN, BP ;
SHEPPARD, RJ ;
SZWARNOWSKI, S .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1978, 11 (05) :695-701