Cu-Al-Fe layered double hydroxides with CO32- and anionic surfactants with different alkyl chains in the interlayer

被引:37
作者
Trujillano, R [1 ]
Holgado, MJ [1 ]
González, JL [1 ]
Rives, V [1 ]
机构
[1] Univ Salamanca, Dept Quim Inorgan, E-37008 Salamanca, Spain
关键词
hybrid organic-inorganic compounds; layered double hydroxides; anionic surfactant; Jahn-Teller effect;
D O I
10.1016/j.solidstatesciences.2005.03.003
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Layered double hydroxides (LDHs), with the hydrotalcite-like structure containing Cu(II), Al(III) and Fe(III) in the layers, and different alkyl sulfonates in the interlayer, have been prepared and characterized by powder X-ray diffraction, FT-IR spectroscopy, differential thermal analysis and thermogravimetric analysis. Pure crystalline phases have been obtained in all cases. Upon heating, combustion of the organic chain takes place at lower temperature than the corresponding sodium salts. (c) 2005 Elsevier SAS. All rights reserved.
引用
收藏
页码:931 / 935
页数:5
相关论文
共 22 条
[1]   [ZN2CR(OH)6]X.2H2O, NEW LAYER COMPOUNDS CAPABLE OF ANION-EXCHANGE AND INTRACRYSTALLINE SWELLING [J].
BOEHM, HP ;
STEINLE, J ;
VIEWEGER, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (04) :265-266
[2]   HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].
Cavani, F. ;
Trifiro, F. ;
Vaccari, A. .
CATALYSIS TODAY, 1991, 11 (02) :173-301
[3]  
Colthup N.B., 1990, INTRO INFRARED RAMAN
[4]   Simultaneous catalytic removal of SOx and NOx with hydrotalcite-derived mixed oxides containing copper, and their possibilities to be used in FCC units [J].
Corma, A ;
Palomares, AE ;
Rey, F ;
Marquez, F .
JOURNAL OF CATALYSIS, 1997, 170 (01) :140-149
[5]  
HERNANDEZMORENO MJ, 1985, PHYS CHEM MINER, V12, P34
[6]   Hybrid organic-inorganic multilayer materials:: influence of π electrons as magnetic media in a series of bridged-layer compounds M2(OH)4-xAx/2 (M = Cu(II) or Co(II), A = dicarboxylate anion) [J].
Hornick, C ;
Rabu, P ;
Drillon, M .
POLYHEDRON, 2000, 19 (03) :259-266
[7]   High-temperature transformations of Cu-rich hydrotalcites [J].
Kannan, S ;
Rives, V ;
Knözinger, H .
JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (01) :319-331
[8]   EFFECT OF HYDROTHERMAL AND THERMAL TREATMENTS ON THE PHYSICOCHEMICAL PROPERTIES OF MG-AL HYDROTALCITE-LIKE MATERIALS [J].
LABAJOS, FM ;
RIVES, V ;
ULIBARRI, MA .
JOURNAL OF MATERIALS SCIENCE, 1992, 27 (06) :1546-1552
[9]   Liquid phase hydrogenation of cinnamaldehyde on Cu-based catalysts [J].
Marchi, AJ ;
Gordo, DA ;
Trasarti, AF ;
Apesteguía, CR .
APPLIED CATALYSIS A-GENERAL, 2003, 249 (01) :53-67
[10]   ANION-EXCHANGE REACTIONS OF LAYERED DOUBLE HYDROXIDES [J].
MEYN, M ;
BENEKE, K ;
LAGALY, G .
INORGANIC CHEMISTRY, 1990, 29 (26) :5201-5207