Crystalline Covalent Organic Frameworks with Hydrazone Linkages

被引：819

作者：

Uribe-Romo, Fernando J. ^{[1
]}

Doonan, Christian J. ^{[1
]}

Furukawa, Hiroyasu ^{[1
]}

Oisaki, Kounosuke ^{[1
]}

Yaghi, Omar M. ^{[1
,2
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Ctr Global Mentoring, Ctr Reticular Chem, Los Angeles, CA 90095 USA

[2] Korea Adv Inst Sci & Technol, Grad Sch EEWS, Taejon 305701, South Korea

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 30期

基金：

日本学术振兴会;

关键词：

RETICULAR SYNTHESIS; HYDROGEN; 2D; ADSORPTION; STORAGE;

D O I：

10.1021/ja204728y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Condensation of 2,5-diethoxyterephthalohydrazide with 1,3,5-triformylbenzene or 1,3,5-tris(4-formylphenyl)benzene yields two new covalent organic frameworks, COF-42 and COF-43, in which the organic building units are linked through hydrazone bonds to form extended two-dimensional porous frameworks. Both materials are highly crystalline, display excellent chemical and thermal stability, and are permanently porous. These new COFs expand the scope of possibilities for this emerging class of porous materials.

引用

收藏

页码：11478 / 11481

页数：4

相关论文

共 33 条

[1] STRUCTURE AND PHOTOCHEMICAL PROPERTIES OF [N'-(2-THIENYLIDENE)]BENZHYDRAZIDE CRYSTALS [J].

ALDOSHIN, SM ;

CHUEV, II ;

ATOVMYAN, LO ;

NEDZVETSKII, VS ;

KULIKOV, AS .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1991, 40 (01) :74-76

[2] CROSS POLARIZATION AND MAGIC ANGLE SAMPLE SPINNING NMR-SPECTRA OF MODEL ORGANIC-COMPOUNDS .1. HIGHLY PROTONATED MOLECULES [J].

ALEMANY, LB ;

GRANT, DM ;

PUGMIRE, RJ ;

ALGER, TD ;

ZILM, KW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (08) :2133-2141

[3]

[Anonymous], 2009, MAT STUD VERS 5 0 0

[4] Adsorption of hydrogen in covalent organic frameworks: Comparison of simulations and experiments [J].

Assfour, Bassem ;

Seifert, Gotthard .

MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 133 (1-3) :59-65

[5] Hydrogen adsorption sites and energies in 2D and 3D covalent organic frameworks [J].

Assfour, Bassem ;

Seifert, Gotthard .

CHEMICAL PHYSICS LETTERS, 2010, 489 (1-3) :86-91

[6] Reticular synthesis of microporous and mesoporous 2D covalent organic frameworks [J].

Cote, Adrien P. ;

El-Kaderi, Hani M. ;

Furukawa, Hiroyasu ;

Hunt, Joseph R. ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (43) :12914-+

[7] Porous, crystalline, covalent organic frameworks [J].

Côté, AP ;

Benin, AI ;

Ockwig, NW ;

O'Keeffe, M ;

Matzger, AJ ;

Yaghi, OM .

SCIENCE, 2005, 310 (5751) :1166-1170

[8] Synthesis of Metallophthalocyanine Covalent Organic Frameworks That Exhibit High Carrier Mobility and Photoconductivity [J].

Ding, Xuesong ;

Guo, Jia ;

Feng, Xiao ;

Honsho, Yoshihito ;

Guo, Jingdong ;

Seki, Shu ;

Maitarad, Phornphimon ;

Saeki, Akinori ;

Nagase, Shigeru ;

Jiang, Donglin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (06) :1289-1293

[9] A Covalent Organic Framework with 4 nm open pores [J].

Dogru, Mirjam ;

Sonnauer, Andreas ;

Gavryushin, Andrei ;

Knochel, Paul ;

Bein, Thomas .

CHEMICAL COMMUNICATIONS, 2011, 47 (06) :1707-1709

[10]

Doonan CJ, 2010, NAT CHEM, V2, P235, DOI [10.1038/nchem.548, 10.1038/NCHEM.548]

← 1 2 3 4 →