Synthesis of 2-fluoroabscisic acid: A potential photo-stable abscisic acid

被引：25

作者：

Kim, BT

Min, YK

Asami, T

Park, NK

Kwon, OY

Cho, KY

Yoshida, S

机构：

[1] RIKEN, INST PHYS & CHEM RES, WAKO, SAITAMA 35101, JAPAN

[2] SOONG SIL UNIV, DEPT CHEM, DONG JAK GU, SEOUL 156743, SOUTH KOREA

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 10期

关键词：

D O I：

10.1016/S0040-4039(97)00172-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel fluorinated abscisic acid (ABA) analogs were synthesized by introducing fluorine through the Wittig reaction of alpha-ionone derivatives with triethyl phosphono-2-fluoroacetate. Molecular orbital calculations showed that the introduction of fluorine at the 2 position stabilized the configuration of the side chain. (C) 1997 Elsevier Science Ltd.

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页码：1797 / 1800

页数：4

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