Synthesis and structural characterisation of [Pd-2(mu-Br)(2)(PBu(t)(3))(2)], an example of a palladium(I)-palladium(I) dimer

被引：90

作者：

Vilar, R

Mingos, DMP

Cardin, CJ

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] UNIV READING,DEPT CHEM,READING RG4 9BB,BERKS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 23期

关键词：

D O I：

10.1039/dt9960004313

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses, spectroscopic characterisation and in one case (X = Br) the single-crystal structure of the novel Pd-I-Pd-I dimers [Pd-2(mu-X)(2)(PBu(3)(t))(2)] (X = Br or I) have been determined; preliminary results on their reactions with CO, H-2, CNC(6)H(3)Me(2) and C2H2 have also been obtained.

引用

页码：4313 / 4314

页数：2

共 19 条

[1] INTIMATE MECHANISM OF OXIDATIVE ADDITION TO ZEROVALENT PALLADIUM COMPLEXES IN THE PRESENCE OF HALIDE-IONS AND ITS RELEVANCE TO THE MECHANISM OF PALLADIUM-CATALYZED NUCLEOPHILIC SUBSTITUTIONS
AMATORE, C
JUTAND, A
SUAREZ, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) : 9531 - 9541
[2] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [PD-4(MU(3)-CH)(MU-CL)(3)(PBU(3)(T))(4)] - A TETRAHEDRAL PALLADIUM CLUSTER-WITH A MU(3)-METHYLIDYNE LIGAND
BURROWS, AD
MINGOS, DMP
MENZER, S
VILAR, R
WILLIAMS, DJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (12): : 2107 - 2108
[3] PREPARATION AND FACILE INTRA-MOLECULAR METALATION REACTIONS OF BIS(TRI-T-BUTYLPHOSPHINE)PLATINUM(II) HYDRIDES
CLARK, HC
GOEL, AB
GOEL, RG
OGINI, WO
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 157 (01) : C16 - C18
[4] DUCRUIX A, 1977, ACTA CRYSTALLOGR B, V33, P3688, DOI 10.1107/S0567740877011868
[5] DIMERIC PALLADIUM(I) COMPLEXES CONTAINING BRIDGING CYCLOPENTADIENYL GROUP
FELKIN, H
TURNER, GK
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 129 (03) : 429 - 436
[6] REACTIONS OF TRI-TERT-BUTYLPHOSPHINE WITH PLATINUM(II) AND PALLADIUM(II) - FACILE INTRAMOLECULAR METALATION OF TRI-TERT-BUTYLPHOSPHINE
GOEL, RG
MONTEMAYOR, RG
[J]. INORGANIC CHEMISTRY, 1977, 16 (09) : 2183 - 2186
[7] AUTOMATIC PROCESSING OF ROTATION DIFFRACTION DATA FROM CRYSTALS OF INITIALLY UNKNOWN SYMMETRY AND CELL CONSTANTS
KABSCH, W
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 : 795 - 800
[8] KELLER E, 1987, SCHAKAL
[9] New insights into structures, stability, and bonding of mu-allyl ligands coordinated with Pd-Pd and Pd-Pt fragments
Kurosawa, H
Hirako, K
Natsume, S
Ogoshi, S
Kanehisa, N
Kai, Y
Sakaki, S
Takeuchi, K
[J]. ORGANOMETALLICS, 1996, 15 (08) : 2089 - 2097
[10] MCPARTLIN M, UNPUB

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