Preparation and characterization of highly ordered vanadium-iron cyanide molecular magnet nanowire arrays

被引：27

作者：

Zhou, PH ^{[1
]}

Xue, DS ^{[1
]}

Luo, HQ ^{[1
]}

Yao, JL ^{[1
]}

Shi, HG ^{[1
]}

机构：

[1] Lanzhou Univ, MOE, Key Lab Magnetism & Magnet Mat, Lanzhou 730000, Peoples R China

来源：

NANOTECHNOLOGY | 2004年 / 15卷 / 01期

关键词：

D O I：

10.1088/0957-4484/15/1/005

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Highly ordered vanadium-iron cyanide molecular magnet nanowire arrays have been prepared for the first time using an electrodepositing technology with two-step anodized anodic aluminium oxide films. Selectable diameters and lengths of the nanowires can be obtained by controlling the diameters of the nanopores in the anodic aluminium oxide films and the electrodepositing time, respectively. X-ray diffraction and transmission electron microscopy measurement results show that the vanadium-iron cyanide nanowires are straight, continuous, and highly crystalline with a face-centred cubic cubic structure of a = 10.14 Angstrom. The x-ray photoelectron system, Mossbauer spectrum and infrared spectrum measurement results indicate that the oxidation state of the metal ions in the vanadium-iron nanowires can be expressed as V4+-CN-Fe2+. The hysteresis loop of the vanadium-iron cyanide nanowires at 1.9 K indicates that there are magnetic exchange interactions between vanadium and iron ions in the nanowires.

引用

页码：27 / 31

页数：5

共 40 条

[1] CHEMICALLY DERIVATIZED NICKEL SURFACES - SYNTHESIS OF A NEW CLASS OF STABLE ELECTRODE INTERFACES [J].

BOCARSLY, AB ;

SINHA, S .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 137 (01) :157-162

[2] ELECTROCHEMISTRY AND ELECTROCHROMISM OF VANADIUM HEXACYANOFERRATE [J].

CARPENTER, MK ;

CONELL, RS ;

SIMKO, SJ .

INORGANIC CHEMISTRY, 1990, 29 (04) :845-850

[3] BORON-NITRIDE NANOTUBES [J].

CHOPRA, NG ;

LUYKEN, RJ ;

CHERREY, K ;

CRESPI, VH ;

COHEN, ML ;

LOUIE, SG ;

ZETTL, A .

SCIENCE, 1995, 269 (5226) :966-967

[4]

DONG SJ, 1986, J ELECTROANAL CHEM, V210, P31

[5]

Duan XF, 2000, ADV MATER, V12, P298, DOI 10.1002/(SICI)1521-4095(200002)12:4<298::AID-ADMA298>3.0.CO

[6]

2-Y

[7] Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices [J].

Duan, XF ;

Huang, Y ;

Cui, Y ;

Wang, JF ;

Lieber, CM .

NATURE, 2001, 409 (6816) :66-69

[8] ELECTROCHROMISM IN THE MIXED-VALENCE HEXACYANIDES .1. VOLTAMMETRIC AND SPECTRAL STUDIES OF THE OXIDATION AND REDUCTION OF THIN-FILMS OF PRUSSIAN BLUE [J].

ELLIS, D ;

ECKHOFF, M ;

NEFF, VD .

JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (09) :1225-1231

[9] A ROOM-TEMPERATURE ORGANOMETALLIC MAGNET BASED ON PRUSSIAN BLUE [J].

FERLAY, S ;

MALLAH, T ;

OUAHES, R ;

VEILLET, P ;

VERDAGUER, M .

NATURE, 1995, 378 (6558) :701-703

[10]

Gates B, 2002, ADV FUNCT MATER, V12, P219, DOI 10.1002/1616-3028(200203)12:3<219::AID-ADFM219>3.0.CO

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