Crystal structure of neptunium(V) acetate [(NpO2)2(OOCCH3)2(H2O)]•2H2O

被引：5

作者：

Andreev, GB

Antipin, MY

Budantseva, NA

Krot, NN

机构：

[1] Russian Acad Sci, Inst Chem Phys, Moscow 119991, Russia

[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 31卷 / 11期

关键词：

Acetate; Physical Chemistry; 2H2O; Crystallization; Crystal Structure;

D O I：

10.1007/s11173-005-0172-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new neptunium(V) complex [(NpO2)(2)(CH3COO)(2)(H2O)] (.) 2H(2)O was synthesized and its crystal structure was determined. The unit cell parameters are: a = 24.007(10) angstrom, b = 6.779(3) angstrom, c = 8.076(3) angstrom, space group Pnma, Z = 4, V = 1314.2(9) angstrom(3), R = 0.049, wR(F-2) = 0.105. The crystal structure of the compound is composed of neutral [(NpO2)(2)(CH3COO)(2)(H2O)] layers and molecules of the water of crystallization. Each of the crystallographically independent neptunoyl ions performs a bidentate function thus forming a composite system of cation-cation bonds.

引用

页码：800 / 803

页数：4